α-D-Glucose: Precise Determination of Crystal and Molecular Structure by Neutron-Diffraction Analysis

Science  26 Feb 1965:
Vol. 147, Issue 3661, pp. 1038-1039
DOI: 10.1126/science.147.3661.1038-a


This analysis provides the first precise crystal and molecular structural parameters for α-D-glucose. The C—C, C—H, and O—H bond lengths deviate only slightly from their means of 1.523 Å, 1.098 Å, and 0.968 Å. The C(1)—O(1) bond length, 1.389 Å, is significantly shorter than the mean value, 1.420 Å, of the other C—O bonds. The valence angle of the ring oxygen is 113.8 degrees.