Report

Formation of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic Solid

See allHide authors and affiliations

Science  20 Dec 2002:
Vol. 298, Issue 5602, pp. 2358-2361
DOI: 10.1126/science.1078481

You are currently viewing the abstract.

View Full Text

Log in to view the full text

Log in through your institution

Log in through your institution

Abstract

We report the direct observation of dioxygen molecules physisorbed in the nanochannels of a microporous copper coordination polymer by the MEM (maximum entropy method)/Rietveld method, using in situ high-resolution synchrotron x-ray powder diffraction measurements. The obtained MEM electron density revealed that van der Waals dimers of physisorbed O2 locate in the middle of nanochannels and form a one-dimensional ladder structure aligned to the host channel structure. The observed O–O stretching Raman band and magnetic susceptibilities are characteristic of the confined O2 molecules in one-dimensional nanochannels of CPL-1 (coordination polymer 1 with pillared layer structure).

  • * To whom correspondence should be addressed. E-mail: Kitagawa{at}sbchem.kyoto-u.ac.jp

View Full Text