Calibration of Sulfate Levels in the Archean Ocean

+ See all authors and affiliations

Science  20 Dec 2002:
Vol. 298, Issue 5602, pp. 2372-2374
DOI: 10.1126/science.1078265

You are currently viewing the abstract.

View Full Text


The size of the marine sulfate reservoir has grown through Earth's history, reflecting the accumulation of oxygen into the atmosphere. Sulfur isotope fractionation experiments on marine and freshwater sulfate reducers, together with the isotope record, imply that oceanic Archean sulfate concentrations were <200 μM, which is less than one-hundredth of present marine sulfate levels and one-fifth of what was previously thought. Such low sulfate concentrations were maintained by volcanic outgassing of SO2 gas, and severely suppressed sulfate reduction rates allowed for a carbon cycle dominated by methanogenesis.

View Full Text