Report

Nanoplasmonic Probes of Catalytic Reactions

Science  20 Nov 2009:
Vol. 326, Issue 5956, pp. 1091-1094
DOI: 10.1126/science.1176593

You are currently viewing the abstract.

View Full Text

Via your Institution

Log in through your institution

Log in through your institution


Abstract

Optical probes of heterogeneous catalytic reactions can be valuable tools for optimization and process control because they can operate under realistic conditions, but often probes lack sensitivity. We have developed a plasmonic sensing method for such reactions based on arrays of nanofabricated gold disks, covered by a thin (~10 nanometer) coating (catalyst support) on which the catalyst nanoparticles are deposited. The sensing particles monitor changes in surface coverage of reactants during catalytic reaction through peak shifts in the optical extinction spectrum. Sensitivities to below 10−3 monolayers are estimated. The capacity of the method is demonstrated for three catalytic reactions, CO and H2 oxidation on Pt, and NOx conversion to N2 on Pt/BaO.

View Full Text