Report

A nonconjugated radical polymer glass with high electrical conductivity

See allHide authors and affiliations

Science  23 Mar 2018:
Vol. 359, Issue 6382, pp. 1391-1395
DOI: 10.1126/science.aao7287

You are currently viewing the abstract.

View Full Text

Log in to view the full text

Log in through your institution

Log in through your institution

Moving charges with radicals

Conducting polymers usually contain backbones with multiple bonds. After chemical doping to remove some of the electrons, charge carriers can move freely. These conjugated backbones can also make the polymers rigid and hard to process. Joo et al. synthesized a redox-active, nonconjugated radical polymer that exhibited high conductivity (see the Perspective by Lutkenhaus). The polymer has a low glass transition temperature, allowing it to form intermolecular percolation networks for electrons.

Science, this issue p. 1391; see also p. 1334

Abstract

Solid-state conducting polymers usually have highly conjugated macromolecular backbones and require intentional doping in order to achieve high electrical conductivities. Conversely, single-component, charge-neutral macromolecules could be synthetically simpler and have improved processibility and ambient stability. We show that poly(4-glycidyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl), a nonconjugated radical polymer with a subambient glass transition temperature, underwent rapid solid-state charge transfer reactions and had an electrical conductivity of up to 28 siemens per meter over channel lengths up to 0.6 micrometers. The charge transport through the radical polymer film was enabled with thermal annealing at 80°C, which allowed for the formation of a percolating network of open-shell sites in electronic communication with one another. The electrical conductivity was not enhanced by intentional doping, and thin films of this material showed high optical transparency.

View Full Text