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Abstract
A new high-temperature superconducting compound system, Ba2Can – 1CunOx[02(n–1) n–Ba] interstitially doped with calcium or (Ca,Cu) has been identified to exhibit a transition temperature up to 126 kelvin, the highest for a superconductor without a volatile toxic element. 02(n–1)n–Ba has body-centered tetragonal symmetry and an unusual charge-reservoir block. The compounds offer interesting opportunities for high-temperature superconductivity science and technology.