Technical Comments

Comment on “Observation of alkaline earth complexes M(CO)8 (M = Ca, Sr, or Ba) that mimic transition metals”

See allHide authors and affiliations

Science  09 Aug 2019:
Vol. 365, Issue 6453, eaay2355
DOI: 10.1126/science.aay2355


Wu et al. (Reports, 31 August 2018, p. 912) claim that recently characterized octacarbonyls of Ca, Sr, and Ba mimic the classical Dewar-Chatt-Duncanson bonding motif of transition metals. This claim, which contradicts known chemistry and computed electron density distributions, originates in the assumption of a flawed reference state for energy decomposition analyses.

View Full Text